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Zaz, M_Zaid; Chin, Wai_Kiat; Viswan, Gauthami; Subedi, Arjun; Mishra, Esha; McElveen, Kayleigh_A; Tamang, Binny; Shapiro, David; N’Diaye, Alpha_T; Lai, Rebecca_Y; et al (, Journal of Physics: Condensed Matter)Abstract Evidence of chirality was observed at the Fe metal center in Fe(III) spin crossover coordination salts [Fe(qsal)2][Ni(dmit)2] and [Fe(qsal)2](TCNQ)2from x-ray absorption (XAS) spectroscopy at the Fe 2p3/2core threshold. Based on the circularly polarized XAS data, the x-ray natural circular dichroism for [Fe(qsal)2][Ni(dmit)2] and [Fe(qsal)2](TCNQ)2is far stronger than seen for [Fe(qsal)2]Cl suggesting this natural circular dichroism signature is a ligand effect rather than a result of just a loss of octahedral symmetry on the Fe core. The larger the chiral effects in the Fe 2p core to bound XAS, the greater the perturbation of the Fe 2p3/2to 2p1/2spin–orbit splitting seen in the XAS spectra.more » « less
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Zielinski, Ruthi; Nguyen, Nhat; Herrington, Bryce; Tarkian, Amir; Taha, Omar; Chin, Wai_Kiat; Mahmood, Ather; Chen, Xiaoqian; Klewe, Christoph; Shafer, Padraic; et al (, Journal of Physics: Condensed Matter)Abstract We study the effect of strain on the magnetic properties and magnetization configurations in nanogranular FexGe films ( ) with and without B20 FeGe nanocrystals surrounded by an amorphous structure. Relaxed films on amorphous silicon nitride membranes reveal a disordered skyrmion phase while films near and on top of a rigid substrate favor ferromagnetism and an anisotropic hybridization of Fedlevels and spin-polarized Gespband states. The weakly coupled topological states emerge at room temperature and become more abundant at cryogenic temperatures without showing indications of pinning at defects or confinement to individual grains. These results demonstrate the possibility to control magnetic exchange and topological magnetism by strain and inform magnetoelasticity-mediated voltage control of topological phases in amorphous quantum materials.more » « less
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